ammonia used in fertilizer

What You Need To Know About Ammonia

Recently, in line with Nigeria’s federal government energy transition agenda, in line with global direction, received a boost on Thursday at the CERAWeek energy conference in Houston, Texas, as the United States Government indicated interest in a bi-lateral partnership that would see the conversion of the enormous gas resources currently being flared to ammonia.

What is Ammonia?

Ammonia (NH3) is one of the most commonly produced industrial chemicals with gas as one of its raw material. It is used in industry and commerce, and also exists naturally in humans and in the environment. Ammonia is essential for many biological processes and serves as a precursor for amino acid and nucleotide synthesis. In the environment, ammonia is part of the nitrogen cycle and is produced in soil from bacterial processes. Ammonia is also produced naturally from decomposition of organic matter, including plants, animals and animal wastes.

Some chemical/physical properties of ammonia are:

  • At room temperature, ammonia is a colorless, highly irritating gas with a pungent, suffocating odor.
  • In pure form, it is known as anhydrous ammonia and is hygroscopic (readily absorbs moisture).
  • Ammonia has alkaline properties and is corrosive.
  • Ammonia gas dissolves easily in water to form ammonium hydroxide, a caustic solution and weak base.
  • Ammonia gas is easily compressed and forms a clear liquid under pressure.
  • Ammonia is usually shipped as a compressed liquid in steel containers.
  • Ammonia is not highly flammable, but containers of ammonia may explode when exposed to high heat.

Read: How Nigerian Plan to Convert Gas Flaring to Ammonia

 

Uses & Benefits of Ammonia

Talking about the uses of ammonia, it is the most important or building-block chemical and in the manufacture of products that people make use of every day. So let’s see where it is used.

  • Ammonia in Industries
  • Agriculture
  • Household Products
  • For Manufacturing Various Compounds
  • Metal Treating
  • Petroleum

Ammonia in Industries
Ammonia is used extensively in several industries. It is used either as a stabilizer, neutralizer or as a source of nitrogen to carry out several functions. Ammonia is used in wastewater treatment, leather, rubber, paper, food and beverage industries. It also is used cold storage or refrigeration systems and in the production of pharmaceuticals. Ammonia is used in the printing as well as cosmetics industries. It is also used in fermentation.

Agriculture
Ammonia is used mainly in Agricultural industries. About 90 percent of all ammonia produced is used in this field. Since, ammonia acts as a rich source of nitrogen and other elements, it is used in fertilizers to basically sustain food production. It is also used in the production of liquid fertilizer solutions consisting of compounds like ammonium nitrate, salts, urea and others. And there’s more. Ammonia is often used as an antifungal agent on certain fruits and as preservatives.

Household Products
Ammonia is one of the main ingredients in a lot of household cleaning products. It is used as a cleaning agent and can be used to remove stains or clean mirrors, tubs, sinks, windows and more. Some other uses include antimicrobial agent or an antiseptic, and ammonia is also used as a fuel.

For Manufacturing Various Compounds
We find uses of Ammonia in the manufacturing of a number of compounds like nitric acid, Hydrogen cyanide, Ammonium carbonate, Phenol, Urea, Amino acids, and a lot of other items.

Metal Treating
Here dissociated ammonia is used in operations like carbo nitriding, nitriding, furnace brazing, bright annealing, sintering, atomic hydrogen welding and other operations.

Petroleum and Mining
In the petroleum industry ammonia is utilized in counterbalancing the acid constituents of oil which is in crude form. It also helps to keep equipment free from corrosion. Additionally, Ammonia is used in the mining industry for extraction of several metals.

 

Read: What Net Zero Emissions is All About 

 

How can people be exposed to Ammonia?

Most people are exposed to ammonia from inhalation of the gas or vapors. Since ammonia exists naturally and is also present in cleaning products, exposure may occur from these sources. The widespread use of ammonia on farms and in industrial and commercial locations also means that exposure can occur from an accidental release or from a deliberate terrorist attack.

Anhydrous ammonia gas is lighter than air and will rise, so that generally it dissipates and does not settle in low-lying areas. However, in the presence of moisture (such as high relative humidity), the liquefied anhydrous ammonia gas forms vapors that are heavier than air. These vapors may spread along the ground or into low-lying areas with poor airflow where people may become exposed.

What is ammonia’s mechanism of action?

Ammonia interacts immediately upon contact with available moisture in the skin, eyes, oral cavity, respiratory tract, and particularly mucous surfaces to form the very caustic ammonium hydroxide. Ammonium hydroxide causes the necrosis of tissues through disruption of cell membrane lipids (saponification) leading to cellular destruction. As cell proteins break down, water is extracted, resulting in an inflammatory response that causes further damage.

What are the immediate health effects of ammonia exposure?

Inhalation: Ammonia is irritating and corrosive. Exposure to high concentrations of ammonia in air causes immediate burning of the nose, throat and respiratory tract. This can cause bronchiolar and alveolar edema, and airway destruction resulting in respiratory distress or failure. Inhalation of lower concentrations can cause coughing, and nose and throat irritation. Ammonia’s odor provides adequate early warning of its presence, but ammonia also causes olfactory fatigue or adaptation, reducing awareness of one’s prolonged exposure at low concentrations.

Children exposed to the same concentrations of ammonia vapor as adults may receive a larger dose because they have greater lung surface area-to-body weight ratios and increased minute volumes-to-weight ratios. In addition, they may be exposed to higher concentrations than adults in the same location because of their shorter height and the higher concentrations of ammonia vapor initially found near the ground.

Skin or eye contact: Exposure to low concentrations of ammonia in air or solution may produce rapid skin or eye irritation. Higher concentrations of ammonia may cause severe injury and burns. Contact with concentrated ammonia solutions such as industrial cleaners may cause corrosive injury including skin burns, permanent eye damage or blindness. The full extent of eye injury may not be apparent for up to a week after the exposure. Contact with liquefied ammonia can also cause frostbite injury.

Ingestion: Exposure to high concentrations of ammonia from swallowing ammonia solution results in corrosive damage to the mouth, throat and stomach. Ingestion of ammonia does not normally result in systemic poisoning.

How is ammonia exposure treated?

There is no antidote for ammonia poisoning, but ammonia’s effects can be treated, and most people recover. Immediate decontamination of skin and eyes with copious amounts of water is very important. Treatment consists of supportive measures and can include administration of humidified oxygen, bronchodilators and airway management. Ingested ammonia is diluted with milk or water.

Will laboratory tests assist in making treatment decisions if someone has been exposed to ammonia?

Laboratory testing for ammonia exposure will not be useful in making emergency treatment decisions. Medical tests that can detect ammonia in blood or urine are available. However, because ammonia is normally found in the body, these test results cannot serve as biomarkers of exposure. After exposure to low levels, ammonia is either rapidly cleared from the body or metabolized to compounds found endogenously at appreciable levels. Clinical indices of body ammonia or nitrogen levels after exposure to exogenous ammonia have shown no or minimal change from prior levels. Exposure to high concentrations is immediately and overtly toxic, generally providing an adequate basis for diagnosis.